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The Supelclean Sulfoxide SPE cartridge is based on a silica-bound sulfoxide group. The electrophilic sulphur centre of Supelclean Sulfoxide interacts selectively with the π-electron system of polychlorinated biphenyls and retards these compared with long-chain hydrocarbons of the oil matrix. Supelclean Sulfoxide was developed specifically for extraction and determination of PCBs from transformer, waste and mineral oils prior to GC-HRMS or GC-MS analyses.
Supelclean does not refer to a single base matrix, but rather to a comprehensive family of SPE products with different retention mechanisms. Conventional LC phases are primarily based on fully porous silica and include reversed-phase, normal-phase, and ion-exchange modifications. The ENVI products complement acid-washed silica materials, cross-linked polymer adsorbents, and various carbon adsorbents. Alumina, Florisil, activated carbon, and zirconium-based materials expand the selection with distinct adsorption and matrix cleanup properties. Multilayer cartridges combine multiple sorbents in a defined sequence. Conditioning, sample pH, solvents, and elution conditions must therefore always be tailored to the specific Supelclean material and the target analytes.
Supelclean is a brand name of Sigma-Aldrich Co. LLC, St. Louis, USA, an affiliate of Merck KGaA, Darmstadt, Germany. ENVI-Carb and ENVI-WAX are also brand names of Merck KGaA or its affiliates. Florisil is a registered trademark of U.S. Silica Company, Frederick, USA.
| Amount | 100 g |
|---|---|
| Brand | Supelclean |
| Product Type | SPE Bulk Sorbent |
| Chemistry Producers Term | Sulfoxide |
| Country of Origin | Germany |
| Mode of Separation | Semipolar Phase Chromatography |
| Matrix | Silica |